Contrasting the group 6 metal–metal bonding in sodium dichromate(ii) and sodium dimolybdate(ii) polymethyl complexes: synthetic, X-ray crystallographic and theoretical studies
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چکیده
منابع مشابه
Contrasting the group 6 metal-metal bonding in sodium dichromate(ii) and sodium dimolybdate(ii) polymethyl complexes: synthetic, X-ray crystallographic and theoretical studies.
Extending the class of group 6 metal-metal bonded methylate compounds supported by alkali metal counter-ions, the first sodium octamethylmolybdate(ii) complex [(TMEDA)Na]4Mo2Me8 and heptamethylchromate(ii) relations [(donor)Na]3Cr2Me7 (donor is TMEDA or TMCDA) are reported. The former was made by treating [(Et2O)Li]4Mo2Me8 with four equivalents of NaOtBu/TMEDA in ether; whereas the latter resul...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2017
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c6dt04644d